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Disconnecting structure and dynamics in glassy thin films

机译:玻璃薄膜中的结构和动力学断开

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摘要

Nanometrically thin glassy films depart strikingly from the behavior of theirbulk counterparts. We investigate whether the dynamical differences betweenbulk and thin film glasses can be understood by differences in localmicroscopic structure. We employ machine-learning methods that have previouslyidentified strong correlations between local structure and particlerearrangement dynamics in bulk systems. We show that these methods completelyfail to detect key aspects of thin-film glassy dynamics. Furthermore, we showthat no combination of local structural features drawn from a very general setof two- and multi-point functions is able to distinguish between particles atthe center of film and those in intermediate layers where the dynamics arestrongly perturbed.
机译:纳米级的玻璃状薄膜明显不同于其同类薄膜的行为。我们调查是否可以通过局部微观结构的差异来理解散装和薄膜玻璃之间的动力学差异。我们采用机器学习方法,该方法先前已确定了散装系统中局部结构与粒子重排动力学之间的强相关性。我们表明,这些方法完全无法检测薄膜玻璃动力学的关键方面。此外,我们表明,从非常通用的两点和多点函数集得出的局部结构特征的组合不能区分膜中心的粒子和动力学受到强烈干扰的中间层的粒子。

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